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Photopolymer Overview

iSQUARED PolyJet Refill compatible with Stratasys Printers

iSQUARED SLA Refill compatible with Formlabs® Printers

SOMOS SLA Materials compatible with Large VAT Printers

ForwardAM Materials compatible with Open SLA Platforms

ForwardAM Material compatible with Open DLP Platforms

Photopolymers for PolyJet, SLA, DLP, and LCD Technologies

Photopolymer-based 3D printing technologies, such as PolyJet, Stereolithography (SLA), Digital Light Processing (DLP), and Liquid Crystal Display (LCD) printing, are widely used in various industries for their ability to produce high-resolution, detailed parts. Unlike thermoplastic-based printing methods like FDM, these technologies rely on liquid photopolymers, which are cured (solidified) layer by layer using ultraviolet (UV) light or a similar light source. The choice of photopolymer resin is crucial for determining the final properties, accuracy, and quality of the printed parts, making it an essential factor in the success of the 3D printing process.

Photopolymers are specially formulated resins that contain monomers and oligomers which react when exposed to light, initiating a curing process that transforms the liquid resin into a solid. The precise control of light exposure allows for the creation of highly detailed objects with smooth surface finishes, often with resolutions far superior to those achieved by other 3D printing methods. However, the performance of the printed parts and the ease of processing depend heavily on the specific type of photopolymer chosen.

PolyJet technology

In PolyJet technology, the printer jets layers of liquid photopolymer onto a build platform, which are immediately cured by UV light. One of the key advantages of PolyJet technology is its ability to print in multiple materials simultaneously, enabling the production of parts with varying material properties within a single print job. This makes PolyJet ideal for applications where flexibility, rigidity, or translucency are required in different parts of the same object. Photopolymers for PolyJet printing need to flow well and maintain consistent viscosity to ensure even deposition during the jetting process. Additionally, the resin must cure quickly under UV light to support the high-speed printing capabilities of this technology.

Stereolithography (SLA)

Stereolithography (SLA) was the first widely adopted photopolymer-based 3D printing method and remains one of the most popular technologies today. In SLA, a laser is used to selectively cure the photopolymer resin layer by layer, building highly accurate parts with excellent surface finishes. SLA resins are chosen based on the application’s mechanical, thermal, or aesthetic requirements. For example, there are resins designed for general-purpose prototyping, which offer ease of printing and good all-around mechanical properties, while others are optimized for high-temperature applications or for producing parts that mimic the flexibility of rubber. SLA resins also vary in terms of post-processing needs, as some require additional UV curing or chemical treatments to achieve their full strength and stability.

Digital Light Processing (DLP) and Liquid Crystal Display (LCD)

Digital Light Processing (DLP) and Liquid Crystal Display (LCD) 3D printing technologies are similar to SLA but use different light sources to cure the photopolymer resin. DLP uses a digital projector to flash an entire layer of the print at once, making it faster than laser-based SLA systems. LCD, on the other hand, utilizes an LCD screen with UV backlighting to expose each layer of the resin. Both methods offer high-resolution printing with excellent surface detail, but the choice of photopolymer resin still plays a pivotal role in determining the part’s final quality and functionality. Resins for DLP and LCD printing are formulated to cure rapidly under their respective light sources while maintaining the necessary mechanical properties to prevent warping, shrinkage, or cracking during the print.

Selection Criteria for Photopolymer Resins

Mechanical Properties of Photopolymer Resins

One of the most important factors in selecting a photopolymer resin is the mechanical properties required for the final part. Resins are available in a wide range of formulations, from rigid and durable materials to flexible and elastic ones. Rigid resins are ideal for creating parts that need high strength and stiffness, such as functional prototypes or production parts. Flexible and elastomeric resins, on the other hand, are used for applications requiring bendability, such as gaskets, seals, or wearable devices. Additionally, there are tough resins designed to resist impact and wear, making them suitable for functional parts that will undergo mechanical stress.

Aesthetic Considerations in Resin Selection

In certain applications, the appearance of the printed part is just as important as its mechanical performance. Photopolymers are available in a variety of colors, as well as clear or translucent formulations. Transparent resins are often used for creating lenses, light guides, or visual prototypes where clarity is essential. Opaque resins, available in standard colors or custom-matched shades, can be used to create visually striking prototypes or finished products. PolyJet technology, in particular, allows for full-color printing by combining different colored resins, making it ideal for producing realistic prototypes or models with detailed color patterns.

Environmental and Chemical Performance of Resins

Beyond mechanical properties and appearance, photopolymer resins are also selected based on their specific environmental or chemical performance. Some resins are designed to be biocompatible, which is crucial for applications in the medical and dental fields where parts must safely come into contact with human skin or bodily fluids. These specialized resins undergo rigorous testing and certification to meet industry standards for biocompatibility. There are also heat-resistant resins that maintain their structural integrity at high temperatures, making them suitable for applications in automotive or aerospace industries where parts are exposed to extreme heat.

Sustainability and Recycling of Photopolymer Resins

Recycling and material sustainability are also growing concerns in the 3D printing industry. Traditional photopolymer resins, once cured, are not recyclable, leading to waste and environmental concerns. However, advancements are being made in developing bio-based or recyclable photopolymer resins that offer more sustainable alternatives without sacrificing performance. These innovations are especially important in industries striving to reduce their carbon footprint while maintaining high manufacturing standards.

Post-Processing of Photopolymer Prints

Another important consideration when working with photopolymers is post-processing. Many photopolymer prints require additional curing after the printing process to reach their full mechanical properties. This can be done using UV curing chambers or other light sources. Additionally, prints may need to be cleaned of excess resin using solvents or water-based cleaning agents, depending on the resin used. Some resins may also require sanding, polishing, or painting to achieve the desired surface finish.

In conclusion, photopolymers are a key material in high-resolution 3D printing technologies like PolyJet, SLA, DLP, and LCD. The choice of photopolymer resin influences the mechanical properties, appearance, and durability of the printed part, making it critical to select the right material for each application. From flexible, rubber-like materials to rigid, high-strength resins, the versatility of photopolymers allows for a wide range of applications across industries such as healthcare, automotive, and consumer goods. As 3D printing technology evolves, the development of new and improved photopolymers will continue to expand the possibilities for additive manufacturing.

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